I'm not against lithium batteries. I just think it's important for people to understand their limitations and risks. I sit with my lithium
battery powered laptop in my lap a lot of the time. However, if it starts getting hot, I'm going to very quickly get away from it and if it starts spitting flame, I'm going to be real careful not to breathe any of the fumes.
I have 2 lithium drill batteries and 4 lithium laptop batteries. One laptop
battery still works, the other 5 batteries are dead. Most of them simply wouldn't work any more one day. The only "abuse" any of them had was going a few months without being charged. Quite a few long term laptop users say they get a year or two out of most laptop batteries.
Many lithium batteries DO have a tendency to burst into flames if you charge/discharge them wrong. Because of this, manufacturers usually design electronic circuits that monitor the charge and discharge cycles. They can detect some warning signs that the
battery is getting dangerous and will "blow an internal fuse" and shut down the
battery where it will no longer accept a charge. With this kind of circuit, lithium
battery packs are a lot less likely to burn.
More than 4 million Sony lithium laptop batteries were
recalled in 2006 because of fire hazard. I believe that Sony changed the charging circuitry later to make this less likely.
The
FAA says "Effective January 1, 2008, you may not pack spare lithium batteries in your checked baggage."
Google or Youtube "lithium
battery fire" for a lot of scary videos.
Lithium batteries are considerably more fire prone than most other batteries because lithium itself is more flammable than other
battery material. Lead, nickel, and cadmium don't usually burn. Other batteries may produce hydrogen which will burn, but they can't contain enough hydrogen gas to make a big fire or explosion, but they can build up gas pressure and make a big bang, spraying acid around.
Manufacturers do a lot to try and reduce the flame/explosion risk, but it's still there to some extent.
Here is a
MSDS for a lithium ion
battery. Note that hydrogen fluoride is one of the possible chemicals released. Hydrogen fluoride rapidly turns into
hydrofluoric acid when it contacts humans. Hydrofluoric acid is particularly nasty because once you get it on you, even if you wash it off, it penetrates tissue and may do internal damage hours later.
Here is the
story with pictures of an explosion of a flashlight with rechargeable lithium batteries. This did NOT have a professionally designed
battery pack, it had individual rechargeable lithium cells.
As I said before, I'm not that worried about commercially available lithium
battery packs. They're a lot like gasoline. I understand that the gas tank in my car can become extremely hazardous. If it catches on fire or develops a serious leak, I'm getting the heck out of there. I'm not going to try to "roll my own" gas tank for my car. I'm careful where I store gasoline around the home.